Codes in Column 7 may be numbers, or a combination of letters and numbers. (iv) The name or symbol of the bottle producer, and the month and year of manufacture, must be marked by embossing, ink-jet printing of permanent ink, or other permanent means on the face or bottom of each bottle, in letters and numbers at least 6 mm (0.2 inch) high. N91 The use of a non specification sift-proof, non-bulk, metal can with or without lid, or a non specification sift-proof, non-bulk fiber drum, with or without lid is authorized when transporting coal tar pitch compounds by motor vehicle or rail freight. 391 Except for articles being transported by motor vehicle as a material of trade in accordance with 173.6 of this subchapter, articles containing hazardous materials of Division 2.3, or Division 4.2, or Division 4.3, or Division 5.1, or Division 5.2, or Division 6.1 (substances with an inhalation toxicity of Packing Group I) and articles containing more than one of the following hazards: (1) Gases of Class 2; (2) Liquid desensitized explosives of Class 3; or (3) Self-reactive substances and solid desensitized explosives of Division 4.1, may only be offered for transportation and transported under conditions approved by the Associate Administrator. Column 4 specifies the applicability of 178.275(g)(3) of this subchapter for the pressure relief devices. in such a manner as to prevent short circuits, accidental operation, and significant movement relative to the cargo transport unit under the shocks, loadings, and vibrations normally incident to transport. 335 Mixtures of solids that are not subject to this subchapter and environmentally hazardous liquids or solids may be classified as Environmentally hazardous substances, solid, n.o.s, UN3077 and may be transported under this entry, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. This is in response to your November 18, 2015 e-mail and subsequent conversations with members of my staff requesting clarification of the Hazardous Materials Regulations (HMR; 49 CFR Parts 171-180) applicable to the selection of a . When column 7 of the 172.101 table refers to a special provision for a hazardous material, the meaning and requirements of that provision are as set forth in this section. The manufacturer must provide such information to a representative of the Department upon request. A bulk packaging containing sulfur is not subject to the placarding requirements of subpart F of this part, if it is marked with the appropriate identification number as required by subpart D of this part. (1) Numeric provisions. Single unit tank car tanks must have a reclosing pressure relief device having a start-to-discharge pressure set at no more than 1551 kPa (225 psig). 74 During transport, this material must be protected from direct sunshine and stored or kept in a cool and well-ventilated place, away from all sources of heat. Example: Yes, I would like to receive emails from Daniels Training Services. [Amdt. Model rocket motors containing 30 grams or less propellant are classed as Division 1.4S and items containing more than 30 grams of propellant but not more than 62.5 grams of propellant are classed as Division 1.4C. B134 For Large Packagings offered for transport by vessel, flexible or fibre inner packagings shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner. If the SADT of the technically pure substance is higher than 75 C, the technically pure substance and formulations derived from it are not self-reactive materials and, if not meeting any other hazard class, are not subject to the requirements of this subchapter. These special provisions are in addition to the standard packaging requirements. The tank car specification may be marked to indicate a test pressure of 20.68 Bar (300 psig). DOT Specification 57 port-able tanks used for the transport by vessel of Class 3, Packaging Group II materials must conform to the fol-lowing: (1) Minimum design pressure. c. The time between offering the material for transportation at the point of origin, and unloading the material at the destination does not exceed 48 hours. TP6 The tank must be equipped with a pressure release device which prevent a tank from bursting under fire engulfment conditions (the conditions prescribed in CGA pamphlet S-1.2 (see 171.7 of this subchapter) or alternative conditions approved by the Associate Administrator may be used to consider the fire engulfment condition), taking into account the properties of the hazardous material to be transported. N75 Packages consisting of tightly closed inner packagings of glass, earthenware or metal, securely cushioned and packed in outer wooden barrels or wooden or fiberboard boxes, capacity not over 2.5 kg (5.5 pounds) net weight, are authorized and need not conform to the requirements of part 178 of this subchapter. Pressure relief devices shall be designed to prevent the entry of foreign matter, the leakage of liquid and the development of any dangerous excess pressure. 328 When lithium metal or lithium ion batteries are contained in the fuel cell system, the item must be described under this entry and the appropriate entries for Lithium metal batteries contained in equipment or Lithium ion batteries contained in equipment. Table I - Maximum Ambient Temperature - Gasoline. Outage must be at least 5 percent at 98 C (208 F). (c)Column 2: Hazardous materials descriptions and proper shipping names. This includes vehicles transported in a packaging. The requirements of 173.24(g)(1) and 173.27(c) do not apply. Refrigerated liquefied gases that are authorized to be transported in portable tanks are specified in tank instruction T75. A metal hydride storage system installed in or intended to be installed in a vehicle or equipment or in vehicle or equipment components must be approved for transport by the Associate Administrator. 157 When transported as a limited quantity or a consumer commodity, the maximum net capacity specified in 173.151(b)(1)(i) of this subchapter for inner packagings may be increased to 5 kg (11 pounds). (See 173.50 of this subchapter.). "Published Edition". 142 These hazardous materials may not be classified and transported unless authorized by the Associate Administrator. 162 This material may be transported under the provisions of Division 4.1 only if it is packed so that at no time during transport will the percentage of diluent fall below the percentage that is stated in the shipping description. The Packing Group assigned will be II or III, according to the classification criteria for either Class 3 or Division 4.1, as appropriate, applied to the base material. (2) They must be packed in strong outer packagings and the completed package must be capable of withstanding a 1.8 meter (5.9 feet) drop without leakage of gas contents from detectors. (d) Used or spent battery exception. b. Lithium batteries conforming to paragraph a. of this special provision must be assigned to UN Nos. ); and. (iii) Constructing the battery with terminals that are recessed or otherwise protected so that the terminals will not be subjected to damage if the package is dropped. A6 For combination packagings, if plastic inner packagings are used, they must be packed in tightly closed metal receptacles before packing in outer packagings. It must be demonstrated that the article relieves its pressure by means of a fire degradable seal or other pressure relief device, in such a way that the pressure receptacle will not fragment and that the article or fragments of the article do not rocket more than 10 meters; and. B68 Sodium must be in a molten condition when loaded and allowed to solidify before shipment. Dry sodium cyanide or potassium cyanide is also permitted in siftproof, water-resistant, fiberboard IBCs when transported in closed freight containers or transport vehicles. subject to the Hazardous Materials Regulations must comply with all applicable requirements of Subpart F [172.500]. Net weight of contents in fiberboard boxes may not exceed 29 kg (64 pounds). 145 This entry applies to formulations that neither detonate in the cavitated state nor deflagrate in laboratory testing, show no effect when heated under confinement, exhibit no explosive power, and are thermally stable (self-accelerating decomposition temperature (SADT) at 60 C (140 F) or higher for a 50 kg (110.2 lbs.) The maximum degree of filling must not exceed the degree of filling determined by the following: tr is the maximum mean bulk temperature during transport, tf is the temperature in degrees celsius of the liquid during filling, and. A8 For combination packagings, if glass inner packagings (including ampoules) are used, they must be packed with cushioning material in tightly closed metal receptacles before packing in outer packagings. result, it may not include the most recent changes applied to the CFR. Each empty bottle must have a minimum weight of not less than 140 grams and a minimum wall thickness of not less than 0.020 inch (0.508 mm). This contact form is only for website help or website suggestions. Other inorganic nitrate salts may replace part of the ammonium nitrate. N86 UN pressure receptacles made of aluminum alloy are not authorized. IBCs are only authorized if approved by the Associate Administrator. The standards for transporting a single bulk hazardous material for blasting by cargo tank motor vehicles (CTMV); and. Such articles must comply with the following requirements: (1) The water capacity of the pressure receptacle must not exceed 0.5 L and the working pressure must not exceed 25 bar at 15 C (59 F); (2) The minimum burst pressure of the pressure receptacle must be at least four times the pressure of the gas at 15 C (59 F); (3) Each article must be manufactured in such a way that unintentional firing or release is avoided under normal conditions of handling, packing, transport and use. (iii) A copy of the test results must be kept on file at each facility where packagings are offered for transportation, and must be made available to a representative of the Department upon request. B61 Written procedures covering details of tank car appurtenances, dome fittings, safety devices, and marking, loading, handling, inspection, and testing practices must be approved by the Associate Administrator before any single unit tank car tank is offered for transportation. b. Equipment powered by lithium metal batteries or lithium ion batteries must be described using the entries Lithium metal batteries contained in equipment or Lithium metal batteries packed with equipment or Lithium ion batteries contained in equipment or Lithium ion batteries packed with equipment, as appropriate. The components may be placed in the same outer packaging provided they will not interact dangerously in the event of leakage. The tank must have been designed and constructed to be capable of withstanding full vacuum. N74 Packages consisting of tightly closed inner containers of glass, earthenware, metal or polyethylene, capacity not over 0.5 kg (1.1 pounds) securely cushioned and packed in outer wooden barrels or wooden or fiberboard boxes, not over 15 kg (33 pounds) net weight, are authorized and need not conform to the requirements of part 178 of this subchapter. No more than four bottles, securely closed with threaded caps, may be packed in each box. (1) Even though certain packagings are specified in this part, it is, nevertheless, the responsibility of the person offering a hazardous material for transportation to ensure that such packagings are compatible with their lading. 156 Asbestos that is immersed or fixed in a natural or artificial binder material, such as cement, plastic, asphalt, resins or mineral ore, or contained in manufactured products is not subject to the requirements of this subchapter. B23 Tanks must be made of steel that is rubber lined or unlined. The guns are packaged in accordance with Packing Method US 1 as specified in 173.62 of this subchapter. Capacitors with an energy storage capacity of 0.3 Wh or less are not subject to the requirements of this subchapter. For transportation by aircraft, the provisions of 173.159(b)(2) apply. b. 422 When labelling is required, the label to be used must be the label shown in 172.447. When a plus sign is assigned to mix- 106 The recognized name of the particular explosive may be specified in addition to the type. The Office of the Federal Register publishes documents on behalf of Federal agencies but does not have any authority over their programs. The inlet to the venting device must be located in the vapor space of the IBC under maximum filling conditions. The only tank car tanks authorized are Class DOT 105 tank cars having a test pressure of 2,069 kPa (300 psig) or greater. (9) W codes. Formulations not meeting these criteria must be transported under the provisions applicable to the appropriate entry in the Organic Peroxide Table in 173.225 of this subchapter. TP25 Sulphur trioxide 99.95% pure and above may be transported in tanks without an inhibitor provided that it is maintained at a temperature equal to or above 32.5 C (90.5 F). A portable tank may be offered for transport after the date of expiry of the last lining inspection for a period not to exceed three months for purposes of performing the next required test or inspection, after emptying but before cleaning. g. The test results shall be documented, shall be traceable, and shall be made available to a representative of the Department upon request. Column 7 of the HMT specifies codes for special provisions applicable to packaging, packaging requirements, certification, and marking or labeling for a hazardous material. Sealed packets and articles containing less than 10 mL of a Class 3 liquid in Packing Group II or III absorbed onto a solid material are not subject to this subchapter provided there is no free liquid in the packet or article. The material is also be subject to operational controls which include not exceeding a temperature of 55C (130F) at the time it is offered or during transportation, not exceeding a transportation time of 24 hours, and drivers transporting spent bleaching earth must be trained in the properties and hazards of the spent bleaching earth. If the air bag inflator unit satisfactorily passes the series 6(c) test, it is not necessary to repeat the test on the air bag module. 170 Air must be eliminated from the vapor space by nitrogen or other means. (6) R codes. (4) IB Codes and IP Codes. The purpose of this article is to explain the meaning of the coding system for the Special Provisions of column 7 in order to facilitate your review and understanding of them and how they may apply to your shipment of a hazardous material. Bulk outer packagings must be liquid tight through design or by the use of lining materials. Lead compounds which, when mixed in a ratio of 1:1,000 with 0.07 M (Molar concentration) hydrochloric acid and stirred for one hour at a temperature of 23 C 2 C, exhibit a solubility of 5% or less are not subject to the requirements of this subchapter unless they meet criteria as another hazard class or division. B33 MC 300, MC 301, MC 302, MC 303, MC 305, MC 306, and DOT 406 cargo tanks equipped with a 1 psig normal vent used to transport gasoline must conform to Table I of this Special Provision. When column 7 of the 172.101 table refers to a special provision for a hazardous material, the meaning and requirements of that provision are as set forth in this section. Only Specifications MC 304, MC 307 or DOT 407 cargo tank motor vehicles are authorized for transportation by vessel. A7 Steel packagings must be corrosion-resistant or have protection against corrosion. If appropriate, a package containing this material must conform to the additional labeling requirements of 172.402 of this subchapter. In accordance with Special Provision 8 in 172.102, which is referenced in Column 7 of the Hazardous Materials Table (HMT; 172.101) for the entry "UN3082, Environmentally hazardous substance, liquid, n.o.s.," a hazardous substance that is not a hazardous waste may be shipped under the shipping description "Other regulated substances . b. These notes are explained at the end of each TABLE. If you would like to comment on the current content, please use the 'Content Feedback' button below for instructions on contacting the issuing agency. 51 This description applies to items previously described as Toy propellant devices, Class C and includes reloadable kits. A37 This entry applies only to a material meeting the definition in 171.8 of this subchapter for self-defense spray. TP19 The calculated wall thickness must be increased by 3 mm at the time of construction. 15 This entry applies to Chemical kits and First aid kits containing one or more compatible items of hazardous materials in boxes, cases, etc. Batteries and battery-powered device(s) containing batteries must be prepared and packaged for transport in a manner to prevent: (2) Short circuits, including but not limited to the following methods: (i) Packaging each battery or each battery-powered device when practicable, in fully enclosed inner packagings made of non-conductive material; (ii) Separating or packaging batteries in a manner to prevent contact with other batteries, devices or conductive materials (e.g., metal) in the packagings; or, (iii) Ensuring exposed terminals or connectors are protected with non-conductive caps, non-conductive tape, or by other appropriate means; and. A3 For combination packagings, if glass inner packagings (including ampoules) are used, they must be packed with absorbent material in tightly closed rigid and leakproof receptacles before packing in outer packagings. not more than 0.1 mL/hour per 30 mL inner packaging at 20 C (68 F) produced from gradual decomposition. 198 Nitrocellulose solutions containing not more than 20% nitrocellulose may be transported as paint, perfumery products, or printing ink, as applicable, provided the nitrocellulose contains no more 12.6% nitrogen (by dry mass). 372 This entry applies to asymmetric capacitors with an energy storage capacity greater than 0.3 Wh. UN2258, 1,2-Propylenediamine: In HM-260B, PHMSA removed special provision A6 from column (7) of the . 49 CFR 172.101 The examination and testing of each lighter design must be performed by a person authorized by the Associate Administrator under the provisions of subpart E of part 107 of this chapter, as specified in 173.308(a)(4). During the course of transportation, these substances must be shaded from direct sunlight and all sources of heat and be placed in adequately ventilated areas. Unlined tanks must be passivated before being placed in service. Essentially, such SSolder complies with RoHS (Restriction of Hazardous Substances) regulations. 387 When materials are stabilized by temperature control, the provisions of 173.21(f) of this subchapter apply. Batteries must be securely cushioned and packed to prevent shifting which could loosen terminal caps or reorient the terminals to produce short circuits. 38 If this material shows a violent effect in laboratory tests involving heating under confinement, the labeling requirements of Special Provision 53 apply, and the material must be packaged in accordance with packing method OP6 in 173.225 of this subchapter. 135 Internal combustion engines installed in a vehicle must be described using Vehicle, flammable gas powered or Vehicle, flammable liquid powered, as appropriate. W10 When offered for transportation by vessel, the use of Large Packagings (see 171.8 of this subchapter) is prohibited. A189 Except where the defining criteria of another class or division are met, concentrations of formaldehyde solution: a. N87 The use of copper valves on UN pressure receptacles is prohibited. meet the venting requirements in 173.24(g) or (2.) (2) An indication of compliance with this special provision must be provided by marking each package with the words not restricted or by including the words not restricted on a transport document such as an air waybill accompanying the shipment. Column 7 of the 172.101 Hazmat Table lists the special provisions that apply to an individual proper shipping name. (3) B codes. W41 When offered for transportation by water, this material must be packaged in bales and be securely and tightly bound with rope, wire or similar means. 11 The hazardous material must be packaged as either a liquid or a solid, as appropriate, depending on its physical form at 55 C (131 F) at atmospheric pressure. 39 This substance may be carried under provisions other than those of Class 1 only if it is so packed that the percentage of water will not fall below that stated at any time during transport. B69 Dry sodium cyanide or potassium cyanide may be shipped in the following sift-proof and weather-resistant packagings: metal covered hopper cars, covered motor vehicles, portable tanks, or non-specification bins. 440 When this material is transported by tank car, the offeror must ensure each tank car is remotely monitored for pressure and location. B3 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks and DOT 57 portable tanks are not authorized. Additionally, self-propelled vehicles or equipment that contain a fuel cell engine must be described using the entries Engine, fuel cell, flammable gas powered or Engine, fuel cell, flammable liquid powered or Vehicle, fuel cell, flammable gas powered or Vehicle, fuel cell, flammable liquid powered, as appropriate. iv. B4 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks are not authorized. The proper shipping name Paint related material, corrosive, flammable may be used for consignments of packages containing Paint, corrosive, flammable and Paint related material, corrosive, flammable in the same package; c. The proper shipping name Paint related material, flammable, corrosive may be used for consignments of packages containing Paint, flammable, corrosive and Paint related material, flammable, corrosive in the same package; and. is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. 137 Cotton, dry; flax, dry; sisal, dry; and tampico fiber, dry are not subject to the requirements of this subchapter when they are baled in accordance with ISO 8115, Cotton Bales - Dimensions and Density (IBR, see 171.7 of this subchapter) to a density of not less than 360 kg/m3 (22.1 lb/ft3) for cotton, 400 kg/m3 (24.97 lb/ft3) for flax, 620 kg/m3 (38.71 lb/ft3) for sisal and 360 kg/m3 (22.1 lb/ft3) for tampico fiber and transported in a freight container or closed transport vehicle. The eCFR is displayed with paragraphs split and indented to follow 48 Mixtures of solids that are not subject to this subchapter and toxic liquids may be transported under this entry without first applying the classification criteria of Division 6.1, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. a. Mixtures of one or more organic lead mixtures (such as tetraethyl lead, triethylmethyl lead, diethyldimethyl lead, ethyltrimethyl lead, and tetramethyl lead) with one or more halogen compounds (such as ethylene dibromide and ethylene dichloride), hydrocarbon solvents or other equally efficient stabilizers; or. Packagings of other material with a small amount of metal, for example metal closures or other metal fittings such as those mentioned in part 178 of this subchapter, are not considered metal packagings. Kits that are carried on board transport vehicles for first aid or operating purposes are not subject to the requirements of this subchapter. TP24 The portable tank may be fitted with a device to prevent the build up of excess pressure due to the slow decomposition of the hazardous material being transported. TP5 For a portable tank used for the transport of flammable refrigerated liquefied gases or refrigerated liquefied oxygen, the maximum rate at which the portable tank may be filled must not exceed the liquid flow capacity of the primary pressure relief system rated at a pressure not exceeding 120 percent of the portable tank's design pressure. Insulation must be at least 100 mm (3.9 inches) except that the insulation thickness may be reduced to 51 mm (2 inches) over the exterior heater coils. You can learn more about the process Specification 110A500W tanks must be stainless steel. Authorized specification bulk outer packagings are UN11G fiberboard intermediate bulk containers (IBC) and UN13H4 woven plastic, coated and with liner flexible intermediate bulk containers (FIBCs) meeting the Packing Group II performance level and lined with a plastic liner of at least 6 mil thickness. Examples of such vehicles are cars, motorcycles, trucks, locomotives, scooters, three- and four-wheeled vehicles or motorcycles, lawn tractors, self-propelled farming and construction equipment, boats, and aircraft. 5. We recommend you directly contact the agency responsible for the content in question. In addition to the packaging required in 173.4a, each glass inner packaging must be placed in a sealed plastic bag compatible with ethylene oxide and capable of containing the contents in the event of breakage or leakage of the glass inner packaging; and.

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